Besides flirtatious messages and jokes, Evans has had a fair share of relationships, which he mostly keeps away from the media.
Throughout his career in the entertainment industry, he has been romantically linked with multiple celebrities, including Lily Collins, Ashley Greene, Amy Smart, Kristin Cavallari, Christina Ricci, Emmy Rossum, Kate Bosworth, Jenny Slate, and Dianna Agron.
Among all his relationships, his rapport with Jessica Biel is considered significant. The pair started dating in 2001 and worked together on projects like London and Cellular during their relationship.
After five years of dating, they were even thinking about getting married and having kids. But, they parted in 2006.